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Solution: Write an equilibrium expression for each chemical equation involving one or

Chapter 15, Problem 46P

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QUESTION:

Write an equilibrium expression for each chemical equation involving one or more solid or liquid reactants or products.

(a) \(\mathrm{HCHO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{H}_{3} \mathrm{O}^{+}(a q)+\mathrm{CHO}_{2}{ }^{-}(a q)\)

(b) \(\mathrm{CO}_{3}{ }^{2-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{HCO}_{3}^{-}(a q)+\mathrm{OH}^{-}(a q)\(

(c) \(2 \mathrm{C}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{CO}(\mathrm{g})\)

(d) \(\mathrm{C}(s)+\mathrm{CO}_{2}(g) \rightleftharpoons 2 \mathrm{CO}(g)\)

Equation Transcription:




Text Transcription:

\mathrm{HCHO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{H}_{3} \mathrm{O}^{+}(a q)+\mathrm{CHO}_{2}{ }^{-}(a q)

\mathrm{CO}_{3}{ }^{2-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{HCO}_{3}^{-}(a q)+\mathrm{OH}^{-}(a q)

2 \mathrm{C}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{CO}(\mathrm{g})

\mathrm{C}(s)+\mathrm{CO}_{2}(g) \rightleftharpoons 2 \mathrm{CO}(g)

Questions & Answers

QUESTION:

Write an equilibrium expression for each chemical equation involving one or more solid or liquid reactants or products.

(a) \(\mathrm{HCHO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{H}_{3} \mathrm{O}^{+}(a q)+\mathrm{CHO}_{2}{ }^{-}(a q)\)

(b) \(\mathrm{CO}_{3}{ }^{2-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{HCO}_{3}^{-}(a q)+\mathrm{OH}^{-}(a q)\(

(c) \(2 \mathrm{C}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{CO}(\mathrm{g})\)

(d) \(\mathrm{C}(s)+\mathrm{CO}_{2}(g) \rightleftharpoons 2 \mathrm{CO}(g)\)

Equation Transcription:




Text Transcription:

\mathrm{HCHO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{H}_{3} \mathrm{O}^{+}(a q)+\mathrm{CHO}_{2}{ }^{-}(a q)

\mathrm{CO}_{3}{ }^{2-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{HCO}_{3}^{-}(a q)+\mathrm{OH}^{-}(a q)

2 \mathrm{C}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{CO}(\mathrm{g})

\mathrm{C}(s)+\mathrm{CO}_{2}(g) \rightleftharpoons 2 \mathrm{CO}(g)

ANSWER:

Solution:

Step 1

Equilibrium expression for each chemical equations are given below:

(a)HCHO2 (aq)+  H2O (l)H3O+ (aq) + CHO2- (aq)

    [H3O+] [CHO2-]

 Keq   =    -------------------

                    [HCHO2]

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