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Consider the reaction. An equilibrium mixture of this reaction at a certain temperature

Chapter 15, Problem 51P

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QUESTION:

Consider the reaction.

                                     \(\mathrm{COCl}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{Cl}_{2}(g)\)

An equilibrium mixture of this reaction at a certain temperature has \(\left[\mathrm{COCl}_{2}\right]=0.225 \mathrm{M},[\mathrm{CO}]=0.105 \mathrm{M}\), and \(\left[\mathrm{Cl}_{2}\right]=0.0844 \mathrm{M}\). What is the value of the equilibrium constant at this temperature?

Equation Transcription:

Text Transcription:

\mathrm{COCl}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{Cl}_{2}(g)

\left[\mathrm{COCl}_{2}\right]=0.225 \mathrm{M},[\mathrm{CO}]=0.105 \mathrm{M}

\left[\mathrm{Cl}_{2}\right]=0.0844 \mathrm{M}

Questions & Answers

QUESTION:

Consider the reaction.

                                     \(\mathrm{COCl}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{Cl}_{2}(g)\)

An equilibrium mixture of this reaction at a certain temperature has \(\left[\mathrm{COCl}_{2}\right]=0.225 \mathrm{M},[\mathrm{CO}]=0.105 \mathrm{M}\), and \(\left[\mathrm{Cl}_{2}\right]=0.0844 \mathrm{M}\). What is the value of the equilibrium constant at this temperature?

Equation Transcription:

Text Transcription:

\mathrm{COCl}_{2}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{Cl}_{2}(g)

\left[\mathrm{COCl}_{2}\right]=0.225 \mathrm{M},[\mathrm{CO}]=0.105 \mathrm{M}

\left[\mathrm{Cl}_{2}\right]=0.0844 \mathrm{M}

ANSWER:

Solution 51P:

Here, we are going to find out the value of equilibrium constant at this temperature.

Step 1:

COCl2(g) ⇆ CO(g) + Cl2(g)

The equilibrium constant for this reaction is

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