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How could the following compounds be synthesized from

Chapter 7, Problem 26P

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QUESTION:

How could the following compounds be synthesized from acetylene?

a. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}\)

b. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}\)

Equation Transcription:

Text Transcription:

CH_3 CH_2 CH_2 C trigram CH

CH_3 CH trigram CH_2

Questions & Answers

QUESTION:

How could the following compounds be synthesized from acetylene?

a. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}\)

b. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}\)

Equation Transcription:

Text Transcription:

CH_3 CH_2 CH_2 C trigram CH

CH_3 CH trigram CH_2

ANSWER:

Solution 26P:

Here, we are going to prepare the products buy using different kind of reagents in presence of ethyne..

Step 1:

(a)

Here, ethyne reacts with NaNH2 to form acetylide anion. Then, propyl bromide reacts with the acetylide anion to form 1-butyne.

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