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Solved: Chlordane, like DDT, is an organohalide that was

Chapter 9, Problem 65P

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QUESTION:

Chlordane, like \(\mathrm{DDT}\), is an organohalide that was used as an insecticide for crops such as corn and citrus and for lawns. In \(1983\), it was banned for all uses except against termites, and in \(1988\) it was banned for use against termites as well. Chlordane can be synthesized from two reactants in one step. One of the reactants is hexachlorocyclopentadiene. What is the other reactant? (Hint : See \(\text{Section} \ 8.19\))

Equation Transcription:

DDT

1983

1988

Section 8.19

Text Transcription:

DDT

1983

1988

Section 8.19

Questions & Answers

QUESTION:

Chlordane, like \(\mathrm{DDT}\), is an organohalide that was used as an insecticide for crops such as corn and citrus and for lawns. In \(1983\), it was banned for all uses except against termites, and in \(1988\) it was banned for use against termites as well. Chlordane can be synthesized from two reactants in one step. One of the reactants is hexachlorocyclopentadiene. What is the other reactant? (Hint : See \(\text{Section} \ 8.19\))

Equation Transcription:

DDT

1983

1988

Section 8.19

Text Transcription:

DDT

1983

1988

Section 8.19

ANSWER:

Solution 65P

Step 1 of 2

Chlordane is synthesized by using the Diels-Alder reaction in a single step. One of the reactant is hexachlorocyclopentadiene. So, the other reactant can be finding by using the Retro Diels-Alder reaction.

Retro Diels-Alder reaction:

One of the reactant is hexachlorocyclopentadiene and the other reactant is 1,4-dichlorocyclopent-1ene.

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