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Identify the ketones responsible for the mass spectra in

Chapter 14, Problem 15P

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QUESTION:

Identify the ketones responsible for the mass spectra in Figure \(14.9\)

Figure 14.9      

The mass spectra for  Problem   \(15\).

Equation Transcription:

Text Transcription:

14.9

15

Questions & Answers

QUESTION:

Identify the ketones responsible for the mass spectra in Figure \(14.9\)

Figure 14.9      

The mass spectra for  Problem   \(15\).

Equation Transcription:

Text Transcription:

14.9

15

ANSWER:

Solution 15P

The Molecular ion peak of unknown compound is 86, which is an even mass number. So it contains Carbon, Hydrogen and Oxygen atoms only.

Know the molecular formula of unknown compound by using molecular mass peak as follows:

Calculate double bond equivalency as follows:

As per the statement of question, unknown compound is a ketone. So there is no chance for ring and double must be with oxygen. Thus, the possible ketones having molecular formula

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