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For each of the following pairs of compounds, name one

Chapter 14, Problem 31P

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QUESTION:

For each of the following pairs of compounds, name one absorption band that could be used to

distinguish between them.

a. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3} \text { and } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}_{3}\)

d. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CCH}_{3} \text { and } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}\)

Equation Transcription:

Text Transcription:

CH_3 CH_2 CH_2 CH_3 and CH_3 CH_2 OCH_3

CH_3 CH_2 C trigram CCH_3 and CH_3 CH_2 C trigram CH

Questions & Answers

QUESTION:

For each of the following pairs of compounds, name one absorption band that could be used to

distinguish between them.

a. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3} \text { and } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}_{3}\)

d. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CCH}_{3} \text { and } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{C} \equiv \mathrm{CH}\)

Equation Transcription:

Text Transcription:

CH_3 CH_2 CH_2 CH_3 and CH_3 CH_2 OCH_3

CH_3 CH_2 C trigram CCH_3 and CH_3 CH_2 C trigram CH

ANSWER:

Solution 31P

a.

The compounds are as follows:

It is an alkane that shows characteristic bands at the following regions:

It is ether that shows characteristic bands at the following regions:

Picture 1

Therefore, the two compounds can be distinguished by the ether  stretching band.

(b)

The compounds are as follows:

Picture 4

It is an ester that shows characteristic bands at the following regions:

Picture 5

Picture 6

It is a carboxylic acid that shows characteristic bands at the following regions:

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