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Chapter 14, Problem 73P

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QUESTION:

The \(IR\) and mass spectra for three different compounds are shown in Figures \(14.53-14.55\) . Identify each compound.

Figure 14.53

Equation Transcription:

Text Transcription:

IR

14.53-14.55

Questions & Answers

QUESTION:

The \(IR\) and mass spectra for three different compounds are shown in Figures \(14.53-14.55\) . Identify each compound.

Figure 14.53

Equation Transcription:

Text Transcription:

IR

14.53-14.55

ANSWER:

Solution 73P

a.

The interpretation of the IR spectrum is as follows:

A strong peak at  that corresponds to the alkyl  stretching.

A strong sharp signal at  that corresponds to the carbonyl stretching (ketone).

A medium intense peak at  that corresponds to the alkyl  bending.

The Mass spectral interpretation is as follows:

 corresponds to the mass of the molecular ion .

 corresponds to the ethyl fragment ion .

 corresponds to the fragment ion .

 corresponds to the fragment ion .

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