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Explain how the following compounds, each with the same

Chapter 15, Problem 20P

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QUESTION:

Explain how the following compounds, each with the same molecular formula, could be distinguished by their \({ }^{1} H\ N M R\) spectra.

Equation Transcription:

Text Transcription:

^1 H NMR

Questions & Answers

QUESTION:

Explain how the following compounds, each with the same molecular formula, could be distinguished by their \({ }^{1} H\ N M R\) spectra.

Equation Transcription:

Text Transcription:

^1 H NMR

ANSWER:

Solution 20P

(a)

The compound is as follows:

The compound has three sets of non-equivalent protons. Hence, relatively shows three peaks in the spectrum.

The protons at a have two adjacent b protons, hence, split by  rule into a triplet at .

The protons at c have two adjacent b protons, hence, split by  rule into a triplet at .

The protons at b have two adjacent a protons and one c proton, hence, split by  rule into a multiplet at .

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