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What is the specific rotation of an equilibrium mixture of

Chapter 21, Problem 27P

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QUESTION:

Problem 27P

What is the specific rotation of an equilibrium mixture of fructose? (Hint : The specific rotation of an equilibrium mixture of glucose is +52.7.)

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QUESTION:

Problem 27P

What is the specific rotation of an equilibrium mixture of fructose? (Hint : The specific rotation of an equilibrium mixture of glucose is +52.7.)

ANSWER:

Solution 27PKetose can also exist in the solution predominantly in the cyclic forms. For example, D-fructose forms a five-membered-ring hemiacetal as a result of the reaction of the reaction of its C-5 OH group with its ketone carbonyl group. Here the -OH group is bonded to the new asymmetric center which is trans to the pr

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