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Solved: Why do vinyl raincoats become brittle as they get

Chapter 27, Problem 41P

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QUESTION:

Problem 41P

Why do vinyl raincoats become brittle as they get old, even if they are not exposed to air or to any pollutants?

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QUESTION:

Problem 41P

Why do vinyl raincoats become brittle as they get old, even if they are not exposed to air or to any pollutants?

ANSWER:

Solution 41P

Materials made from polyvinyls are usually hard and brittle. This is a result of the individual polymer strands adopting a very regular, well-organized packing diagram in the solid state. The favorable van der Walls interactions between the strands make the material brittle.

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