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How could head-to-head poly(vinyl bromide) be synthesized?

Chapter 27, Problem 44P

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QUESTION:

How could head-to-head poly(vinyl bromide) be synthesized?

                 

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QUESTION:

How could head-to-head poly(vinyl bromide) be synthesized?

                 

ANSWER:

Solution  44P

Polyvinyl bromide can be synthesized from the monomer unit vinyl bromide . Satirically it is preferred to from. Head to tail linkage But -some times to head and tail to tail  tio linkage is possible

The mechanism of the formation of head to head linkage in polyvinyl bromide iv explained as follows

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