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Account for the difference in the products obtained under

Chapter 28, Problem 15P

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QUESTION:

Account for the difference in the products obtained under photochemical and thermal

conditions:

Questions & Answers

QUESTION:

Account for the difference in the products obtained under photochemical and thermal

conditions:

ANSWER:

Solution 15P

Step 1 of 3

According to wood ward- Hoffmann rules

Number of pairs of electrons in the reacting system

Reaction conditions

Allowed mode of rearrangement

Even number

Thermal

Anthrafacial

Photochemical

Suprafacial

Odd number

Thermal

Suprafacial

Photochemical

Anthrafacial

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