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Solved: If the compounds shown here are heated, one will
Chapter 28, Problem 32P(choose chapter or problem)
If the compounds shown here are heated, one will form one product from a [1,3] sigmatropic rearrangement and the other will form two products from two different [1,3] sigmatropic rearrangements. Draw the products of the reactions.
Questions & Answers
QUESTION:
If the compounds shown here are heated, one will form one product from a [1,3] sigmatropic rearrangement and the other will form two products from two different [1,3] sigmatropic rearrangements. Draw the products of the reactions.
ANSWER:
Solution 32P
Step 1 of 3
[1,3] sigmatropic rearrangement involves one “” bond and one
bond, hence it follows the anthrafacial mode of rearrangement.
Under thermal conditions the following compounds, gives the products.
