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If isomer A is heated to about 100 a mixture of isomers A

Chapter 28, Problem 39P

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QUESTION:

If isomer A is heated to about \(100^{\circ} \mathrm{C}\) , a mixture of isomers A and B is formed. Explain why there is no trace of isomer C or D.

                             

Equation Transcription:

100 °C

Text Transcription:

100 degree C

Questions & Answers

QUESTION:

If isomer A is heated to about \(100^{\circ} \mathrm{C}\) , a mixture of isomers A and B is formed. Explain why there is no trace of isomer C or D.

                             

Equation Transcription:

100 °C

Text Transcription:

100 degree C

ANSWER:

Solution 39P

Under thermal conditions  both HOMO of the diene system  is “2”. In this conditions the ring opening and ring closing av follows conrotatory pathways:

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