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Predict the products of reaction of pent-1-yne with the

Chapter 21, Problem 33SP

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QUESTION:

Problem 33SP

Predict the products of reaction of pent-1-yne with the following reagents.

(a) 1 equivalent of HCl

(b) 2 equivalents of HCl

(c) Excess H2, Ni

(d) H2, Pd/BaSO4, quinolone

(e) 1 equivalent of Br2

(f) 2 equivalents of Br2

(g) cold, dilute KMnO4

(h) warm, concd. KMnO4,NaOH

(i) Na, liquid ammonia

(j) NaNH2

(k) H2SO4/HgSO4,H2O

(l) Sia2BH, then H2O2, -OH

Questions & Answers

QUESTION:

Problem 33SP

Predict the products of reaction of pent-1-yne with the following reagents.

(a) 1 equivalent of HCl

(b) 2 equivalents of HCl

(c) Excess H2, Ni

(d) H2, Pd/BaSO4, quinolone

(e) 1 equivalent of Br2

(f) 2 equivalents of Br2

(g) cold, dilute KMnO4

(h) warm, concd. KMnO4,NaOH

(i) Na, liquid ammonia

(j) NaNH2

(k) H2SO4/HgSO4,H2O

(l) Sia2BH, then H2O2, -OH

ANSWER:

Solution:

Step 1

  1. Reaction between pent-1-yne with  1 equivalent of HCl

(pent-1-yne )

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