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Circle the member of each pair that is more soluble in

Chapter 23, Problem 18P

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QUESTION:

Circle the member of each pair that is more soluble in water.

(a)  \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}_{2} \mathrm{CH}_{3} \text { or } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}\)

(b)  \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}_{2} \mathrm{CH}_{3} \text { or } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\)

(c)  \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{NHCH}_{3} \text { or } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}\)

(d)  \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH} \text { or } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\)

Equation Transcription:

 

Text Transcription:

CH_{3}CH_{2}OCH_{2}CH_{3} or CH_{3}CH_{2}CH_{2}CH_{2}CH_{3}

CH_{3}CH_{2}OCH_{2}CH_{3} or CH_{3}CH_{2}CH_{2}OH

CH_{3}CH_{2}NHCH_{3} or CH_{3}CH_{2}CH_{2}CH_{3}

CH_{3}CH_{2}OH or CH_{3}CH_{2}CH_{2}CH_{2}OH

H_{3}C

CH_{3}

Questions & Answers

QUESTION:

Circle the member of each pair that is more soluble in water.

(a)  \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}_{2} \mathrm{CH}_{3} \text { or } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}\)

(b)  \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}_{2} \mathrm{CH}_{3} \text { or } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\)

(c)  \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{NHCH}_{3} \text { or } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}\)

(d)  \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH} \text { or } \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\)

Equation Transcription:

 

Text Transcription:

CH_{3}CH_{2}OCH_{2}CH_{3} or CH_{3}CH_{2}CH_{2}CH_{2}CH_{3}

CH_{3}CH_{2}OCH_{2}CH_{3} or CH_{3}CH_{2}CH_{2}OH

CH_{3}CH_{2}NHCH_{3} or CH_{3}CH_{2}CH_{2}CH_{3}

CH_{3}CH_{2}OH or CH_{3}CH_{2}CH_{2}CH_{2}OH

H_{3}C

CH_{3}

ANSWER:

Solution 18P :

Step 1:

Here, we have to circle the member of each pair that is more soluble in water.

The factors that affect the solubility of the hydrocarbons are the intermolecular forces acting on the molecule, number of carbon atoms in the molecule, ability to form hydrogen bonds with water.    

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