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Give the structures of the intermediates and products V

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr ISBN: 9780321768414 33

Solution for problem 53SP Chapter 11

Organic Chemistry | 8th Edition

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Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Organic Chemistry | 8th Edition

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Problem 53SP

Give the structures of the intermediates and products V through Z.

Equation Transcription:

Text Transcription:

OH

PBr_3

Mg

H_{3}O^+

CH_{3}C-Cl

Na_{2}Cr_{2}O_7

H_{2}SO_4

Step-by-Step Solution:
Step 1 of 3

Solution 53SP

Phosphorus tribromide is often the beat reagent for converting a primary or secondary alcohol to the alkyl bromide.

Secondary alcohols are easily oxidized to give excellent yields of ketones. The chromic acid reagent is often best for laboratory oxidations of secondary alcohols.

Organomagnesium are formed by the reaction of alkyl halides with magnesium metal.

Typical solvents are normally anhydrous diethyl ether or tetrahydrofuran.

Addition of cyclopentyl magnesium bromide to cyclopentanone gives product Y

An alcohol reacts with an acid chloride in an exothermic reaction to give an ester.

Step 2 of 3

Chapter 11, Problem 53SP is Solved
Step 3 of 3

Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

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Give the structures of the intermediates and products V