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The three isomers of dimethylbenzene are commonly named

Chapter 18, Problem 49SP

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QUESTION:

The three isomers of dimethylbenzene are commonly named ortho-xylene, meta-xylene, and para-xylene. These three isomers are difficult to distinguish using proton NMR, but they are instantly identifiable using \(\mathrm {^{13}C\ NMR}\).

(a) Describe how carbon NMR distinguishes these three isomers.

(b) Explain why they are difficult to distinguish using proton NMR.

Equation Transcription:

Text Transcription:

 13C NMR

CH3

CH3

CH3

CH3

H3C

Questions & Answers

QUESTION:

The three isomers of dimethylbenzene are commonly named ortho-xylene, meta-xylene, and para-xylene. These three isomers are difficult to distinguish using proton NMR, but they are instantly identifiable using \(\mathrm {^{13}C\ NMR}\).

(a) Describe how carbon NMR distinguishes these three isomers.

(b) Explain why they are difficult to distinguish using proton NMR.

Equation Transcription:

Text Transcription:

 13C NMR

CH3

CH3

CH3

CH3

H3C

ANSWER:

Solution 49SP

The three isomers of dimethyl benzene can be distinguished by the  NMR spectroscopy by its chemical shift position as -

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