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For each of the following compounds,1. Give the

Chapter 23, Problem 27SP

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QUESTION:

For each of the following compounds,

1. Give the hybridization and approximate bond angles around each atom except hydrogen.

2. Draw a three-dimensional diagram, including any lone pairs of electrons.

(a) \(\mathrm{H}_{3} \mathrm{O}^{+}\)

(b) \({ }^{-} \mathrm{OH}\)

(c) \(\mathrm{CH}_{2} \mathrm{CHCN}\)

(d) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\)

(e) \({\left[\mathrm{CH}_{3} \mathrm{NH}_{3}\right]^{+}}\)

(f) \(\mathrm{CH}_{3} \mathrm{COOH}\)

(g) \(\mathrm{CH}_{3} \mathrm{CHNH}\)

(h) \(\mathrm{CH}_{3} \mathrm{OH}\)

(i) \(\mathrm{CH}_{2} \mathrm{O}\)

Equation Transcription:

Text Transcription:

H_{3}O^+

^{-}OH

CH_{2}CHCN

(CH_{3})_{3}N

[CH_{3}NH_{3}]^+

CH_{3}COOH

CH_{3}CHNH

CH_{3}OH

CH_{2}O

Questions & Answers

QUESTION:

For each of the following compounds,

1. Give the hybridization and approximate bond angles around each atom except hydrogen.

2. Draw a three-dimensional diagram, including any lone pairs of electrons.

(a) \(\mathrm{H}_{3} \mathrm{O}^{+}\)

(b) \({ }^{-} \mathrm{OH}\)

(c) \(\mathrm{CH}_{2} \mathrm{CHCN}\)

(d) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}\)

(e) \({\left[\mathrm{CH}_{3} \mathrm{NH}_{3}\right]^{+}}\)

(f) \(\mathrm{CH}_{3} \mathrm{COOH}\)

(g) \(\mathrm{CH}_{3} \mathrm{CHNH}\)

(h) \(\mathrm{CH}_{3} \mathrm{OH}\)

(i) \(\mathrm{CH}_{2} \mathrm{O}\)

Equation Transcription:

Text Transcription:

H_{3}O^+

^{-}OH

CH_{2}CHCN

(CH_{3})_{3}N

[CH_{3}NH_{3}]^+

CH_{3}COOH

CH_{3}CHNH

CH_{3}OH

CH_{2}O

ANSWER:

Solution 27SP

Step 1

(a) :

1. The hybridization of the oxygen atom in is , and the bond angle is .

2. The three-dimensional diagram for the given compound is shown as follows:

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