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Determine the ratios of the peak areas in the following

Chapter 18, Problem 6P

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QUESTION:

Determine the ratios of the peak areas in the following spectra. Then use this information,

together with the chemical shifts, to pair up the compounds with their spectra. Assign

the peaks in each spectrum to the protons they represent in the molecular structure.

Possible structures:

Equation Transcription:

Text Transcription:

CH_3

CH_3

CH_{3}O

OCH_3

C{equiv}C-H

OH

CH_{3}-C-C{equiv}C-H

CH_3

Br

CH_{3}-CH-CH_{2}-CH_{3}

CH_3

Br-C-C-CH{3}

Br

delta(ppm)

delta(ppm)

delta(ppm)

Questions & Answers

QUESTION:

Determine the ratios of the peak areas in the following spectra. Then use this information,

together with the chemical shifts, to pair up the compounds with their spectra. Assign

the peaks in each spectrum to the protons they represent in the molecular structure.

Possible structures:

Equation Transcription:

Text Transcription:

CH_3

CH_3

CH_{3}O

OCH_3

C{equiv}C-H

OH

CH_{3}-C-C{equiv}C-H

CH_3

Br

CH_{3}-CH-CH_{2}-CH_{3}

CH_3

Br-C-C-CH{3}

Br

delta(ppm)

delta(ppm)

delta(ppm)

ANSWER:

Solution 6P

Step 1

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