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A compound was isolated as a minor constituent in an

Chapter 18, Problem 47SP

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QUESTION:

A compound was isolated as a minor constituent in an extract from garden cress. Its spectra are shown here.

(1) Look at each spectrum individually, and list the structural characteristics you can determine from that spectrum.

(2) Look at the set of spectra as a group, and propose a tentative structure.

(3) Verify that your proposed structure accounts for the major features of each spectrum.

Equation Transcription:

Text Transcription:

117 M^+

m/z

({mu}m)

(cm^{-1})

delta(ppm)

Questions & Answers

QUESTION:

A compound was isolated as a minor constituent in an extract from garden cress. Its spectra are shown here.

(1) Look at each spectrum individually, and list the structural characteristics you can determine from that spectrum.

(2) Look at the set of spectra as a group, and propose a tentative structure.

(3) Verify that your proposed structure accounts for the major features of each spectrum.

Equation Transcription:

Text Transcription:

117 M^+

m/z

({mu}m)

(cm^{-1})

delta(ppm)

ANSWER:

Solution 47SP

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