How Close Together Are Gas Molecules? Consider an ideal

Chapter 18, Problem 28E

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QUESTION:

How Close Together Are Gas Molecules? Consider an ideal gas at \(27^{\circ} \mathrm{\ C}\) and 1.00 atm pressure. To get some idea how close these molecules are to each other, on the average, imagine them to be uniformly spaced, with each molecule at the center of a small cube. (a) What is the length of an edge of each cube if adjacent cubes touch but do not overlap? (b) How does this distance compare with the diameter of a typical molecule? (c) How does their separation compare with the spacing of atoms in solids, which typically are about 0.3 nm apart?

Text Transcription:

27^circ C

Questions & Answers

QUESTION:

How Close Together Are Gas Molecules? Consider an ideal gas at \(27^{\circ} \mathrm{\ C}\) and 1.00 atm pressure. To get some idea how close these molecules are to each other, on the average, imagine them to be uniformly spaced, with each molecule at the center of a small cube. (a) What is the length of an edge of each cube if adjacent cubes touch but do not overlap? (b) How does this distance compare with the diameter of a typical molecule? (c) How does their separation compare with the spacing of atoms in solids, which typically are about 0.3 nm apart?

Text Transcription:

27^circ C

ANSWER:

Solution 28E

Step 1 of 4:

(a) What is the length of an edge of each cube if adjacent cubes touch but do not overlap?

From ideal gas equation,

                                        PV =NkT

Where P, V and T are the pressure ,volume and  temperature of gas, N is number of molecules.

Since here it is given that, for each cube, N= 1 molecule

Volume of one such cube, V=

Pressure, P=1 atm =1.01

Temperature, T= 27= 300 k

boltzmann constant, k=1.38

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