Intermolecular Forces (Section)Propyl alcohol

Chapter 11, Problem 23E

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Butane and 2-methylpropane, whose space-filling models are shown at the top of the next column, are both nonpolar and have the same molecular formula, C4H10, yet butane has the higher boiling point (-0.5 °C compared to -11.7 °C). Explain.

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