Solved: Color and Magnetism in Coordination Chemistry;

Chapter 13, Problem 51E

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Problem 51E

Color and Magnetism in Coordination Chemistry; Crystal-Field Theory (Sections)

(a) Sketch a diagram that shows the definition of the crystal- field splitting energy (Δ) for an octahedral crystal field. (b) What is the relationship between the magnitude of Δ and the energy of the d-d transition for a d1 complex? (c) Calculate Δ in kJ>mol if a d1 complex has an absorption maximum at 545 nm.

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