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Answer: Find the temperatures at which reactions with the

Chapter 17, Problem 20P

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QUESTION:

Find the temperatures at which reactions with the following \(\Delta H\) and \(\Delta S\) values would become spontaneous:

(a) \(\Delta H=-126 \mathrm{~kJ} / \mathrm{mol}, \Delta S=84 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol};\)

(b) \(\Delta H=-11.7 \mathrm{~kJ} / \mathrm{mol}, \Delta S=-105 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol}\)

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QUESTION:

Find the temperatures at which reactions with the following \(\Delta H\) and \(\Delta S\) values would become spontaneous:

(a) \(\Delta H=-126 \mathrm{~kJ} / \mathrm{mol}, \Delta S=84 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol};\)

(b) \(\Delta H=-11.7 \mathrm{~kJ} / \mathrm{mol}, \Delta S=-105 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol}\)

ANSWER:

Step 1 of 3

The change in free energy of the system can be calculated by the following formula;

                                           ..........................(1)

Here,




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