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The [Ni(CN)4]2– ion, which has a square-planar geometry,

Chapter 23, Problem 33P

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QUESTION:

The \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) ion, which has a square-planar geometry, is diamagnetic, whereas the \(\left[\mathrm{NiCl}_{4}\right]^{2-}\) ion, which has a tetrahedral geometry, is paramagnetic. Show the crystal field splitting diagrams for those two complexes.

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QUESTION:

The \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) ion, which has a square-planar geometry, is diamagnetic, whereas the \(\left[\mathrm{NiCl}_{4}\right]^{2-}\) ion, which has a tetrahedral geometry, is paramagnetic. Show the crystal field splitting diagrams for those two complexes.

ANSWER:

Step 1 of 3

From the given,

The complex - ;

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