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The [Ni(CN)4]2– ion, which has a square-planar geometry,
Chapter 23, Problem 33P(choose chapter or problem)
QUESTION:
The \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) ion, which has a square-planar geometry, is diamagnetic, whereas the \(\left[\mathrm{NiCl}_{4}\right]^{2-}\) ion, which has a tetrahedral geometry, is paramagnetic. Show the crystal field splitting diagrams for those two complexes.
Questions & Answers
QUESTION:
The \(\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}\) ion, which has a square-planar geometry, is diamagnetic, whereas the \(\left[\mathrm{NiCl}_{4}\right]^{2-}\) ion, which has a tetrahedral geometry, is paramagnetic. Show the crystal field splitting diagrams for those two complexes.
ANSWER:Step 1 of 3
From the given,
The complex - ;