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Dimensional Analysis (Section)The distance from Grand

Chemistry: The Central Science | 13th Edition | ISBN: 9780321910417 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus ISBN: 9780321910417 77

Solution for problem 50E Chapter 1

Chemistry: The Central Science | 13th Edition

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Chemistry: The Central Science | 13th Edition | ISBN: 9780321910417 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus

Chemistry: The Central Science | 13th Edition

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Problem 50E

Dimensional Analysis (Section)

The distance from Grand Rapids, Michigan, to Detroit is listed in a road atlas as 153 miles. Describe some of the factors that contribute to the uncertainty in this number. To make the number more precise, what would you need to specify and measure?

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Organic Chem Notes 10/26/17­11/2/17  Carbocation stability trend o Tertiary and secondary allylic/benzylic > secondary and primary allylic/benzylic > primary > methyl  Carbocation rearrangement o A carbocation always tries to be tertiary o HEAR ALARMS when you see a secondary carbocation (might be able to rearrange) o Rules:  Can perform a methyl (CH3) shift or hydride (H+) shift  Can only move these things from neighboring carbons  CANNOT do multiple rearrangements  Leaving Group: stable anions o Cl­ Br­ I­ o F­ is not a good LG because it is highly reactive (very unstable) o Strong bases are

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Chapter 1, Problem 50E is Solved
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Textbook: Chemistry: The Central Science
Edition: 13
Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus
ISBN: 9780321910417

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Dimensional Analysis (Section)The distance from Grand