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Predict the major product for each proposed Diels–Alder

Chapter 9, Problem 16P

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QUESTION:

Predict the major product for each proposed Diels–Alder reaction. Include stereochemistry where appropriate.

Equation Transcription:

Text Transcription:

C \equiv N

CH_3O

CH_3

Ph

Ph

Questions & Answers

QUESTION:

Predict the major product for each proposed Diels–Alder reaction. Include stereochemistry where appropriate.

Equation Transcription:

Text Transcription:

C \equiv N

CH_3O

CH_3

Ph

Ph

ANSWER:

Solution 16P

Diels-Alder reaction: The cyclo addition reaction of diene with a dienophile yields a cyclo hexene.

Example: 1,3 butadiene undergoes cyclo addition reaction with ethylene (diene) to form a cyclohexene. This reaction takes place through a six membered cyclic transition state.

The reaction as follows:

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