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Predict the products of the following Diels–Alder

Chapter 9, Problem 18P

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QUESTION:

Predict the products of the following Diels–Alder reactions.

Equation Transcription:

Text Transcription:

CH_3O

COOCH_3

OCH_3

CH_3O

CHO

CH_3

CH_3

Questions & Answers

QUESTION:

Predict the products of the following Diels–Alder reactions.

Equation Transcription:

Text Transcription:

CH_3O

COOCH_3

OCH_3

CH_3O

CHO

CH_3

CH_3

ANSWER:

Solution 18P

Step 1

(a)

Treatment of 2-methoxycyclopenta-1,3-diene (diene) with methyl propiolate (dienophile) forms new carbon-carbon bond in the product. Thus, the reaction is as follows:

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