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Solved: Predict the products of the following Diels–Alder

Chapter 9, Problem 30SP

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QUESTION:

Predict the products of the following Diels–Alder reactions. Include stereochemistry where appropriate.

Equation Transcription:

Text Transcription:

OH

COOCH_3

COOH

OCH_3

CHO

CN

CN

CN

CN

Questions & Answers

QUESTION:

Predict the products of the following Diels–Alder reactions. Include stereochemistry where appropriate.

Equation Transcription:

Text Transcription:

OH

COOCH_3

COOH

OCH_3

CHO

CN

CN

CN

CN

ANSWER:

Solution 30SP

(a) Treatment of buta-1,3-diene with acrylic acid gives cyclohex-3-enecarboxylic acid.

(b) Treatment of cyclohex-1,3 diene with methyl propiolate gives the endo product.

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