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Show how Diels–Alder reactions might be used to synthesize

Chapter 9, Problem 33SP

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QUESTION:

Show how Diels–Alder reactions might be used to synthesize the following compounds.

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QUESTION:

Show how Diels–Alder reactions might be used to synthesize the following compounds.

ANSWER:

Step 1 of 10

Diels-Alder reaction: The cyclo addition reaction of a diene with a dienophile yields a cyclo hexene. 1,3 butadiene undergoes cyclo addition reaction with ethylene (diene) to form cyclohexene. This reaction takes place through a six-membered cyclic transition state.

The reaction is as follows:

       

Step 2 of 10

(a)  The target Diels-Alder product can be synthesized using the following diene and dienophile. The reaction is as follows:

      

Step 3 of 10

(b)  The target Diels-Alder product can be synthesized using the following diene and dienophile. The reaction is as follows:

    

Step 4 of 10

(c)  The target Diels-Alder produc

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