The standard heat of the reaction CaCz(s) + 5 HzO(1)

Chapter 9, Problem 9.4

(choose chapter or problem)

The standard heat of the reaction CaCz(s) + 5 HzO(1) -----+ CaO(s) + 2 COz(g) + 5 H2(g) is D.fi~ = +69.36 klima!. (a) Is the reaction exothermic or endothermic at 25C? Would you have to heat or cool the reactor to keep the temperature constant? What would the temperature do if the reactor ran adiabatically? What can you infer about the energy required to break the molecular bonds of the reactants and that released when the product bonds form? (b) Calculate D.O~ for this reaction. (See Example 9.1-2.) Briefly explain the physical significance of your calculated value. (c) Suppose you charge 150.0 g of CaCz and liquid water into a rigid container at 25C, heat the container until the calcium carbide reacts completely, and cool the products back down to 25C, condensing essentially all the unconsumed water. Write and simplify the energy balance 477 equation for this closed constant-volume system and use it to determine the net amount of heat (kl) that must be transferred to or from the reactor (state which)