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Two structures for the sugar glucose are shown on page

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr ISBN: 9780321768414 33

Solution for problem 62SP Chapter 18

Organic Chemistry | 8th Edition

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Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Organic Chemistry | 8th Edition

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Problem 62SP

Problem 62SP

Two structures for the sugar glucose are shown on page 858. Interconversion of the open-chain and cyclic hemiacetal forms is catalyzed by either acid or base.

(a) Propose a mechanism for the cyclization, assuming a trace of acid is present.

(b) The cyclic hemiacetal is more stable than the open-chain form, so very little of the open-chain form is present at equilibrium. Will an aqueous solution of glucose reduce Tollens reagent and give a positive Tollens test? Explain.

Step-by-Step Solution:
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Solution 62SP

a.

b.

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Chapter 18, Problem 62SP is Solved
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Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. The answer to “Two structures for the sugar glucose are shown on page 858. Interconversion of the open-chain and cyclic hemiacetal forms is catalyzed by either acid or base.(a) Propose a mechanism for the cyclization, assuming a trace of acid is present.(b) The cyclic hemiacetal is more stable than the open-chain form, so very little of the open-chain form is present at equilibrium. Will an aqueous solution of glucose reduce Tollens reagent and give a positive Tollens test? Explain.” is broken down into a number of easy to follow steps, and 76 words. Organic Chemistry was written by and is associated to the ISBN: 9780321768414. This full solution covers the following key subjects: Chain, open, acid, tollens, interconversion. This expansive textbook survival guide covers 25 chapters, and 1336 solutions. Since the solution to 62SP from 18 chapter was answered, more than 356 students have viewed the full step-by-step answer. The full step-by-step solution to problem: 62SP from chapter: 18 was answered by , our top Chemistry solution expert on 05/06/17, 06:41PM.

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Two structures for the sugar glucose are shown on page