In calculated the pressure of earth’s atmosphere as a

Chapter 1, Problem 40P

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QUESTION:

Problem 40P

In Problem you calculated the pressure of earth’s atmosphere as a function of altitude, assuming constant temperature. Ordinarily, however, the temperature of the bottommost 10–15 km of the atmosphere (called the troposphere) decreases with increasing altitude, due to heating from the ground (which is warmed by sunlight). If the temperature gradient |dT/dz| exceeds a certain critical value, convection will occur: Warm, low-density air will rise, while cool, high-density air sinks. The decrease of pressure with altitude causes a rising air mass to expand adiabatically and thus to cool. The condition for convection to occur is that the rising air mass must remain warmer than the surrounding air despite this adiabatic cooling.

(a) Show that when an ideal gas expands adiabatically, the temperature and pressure are related by the differential equation

(b) Assume that dT/dz is just at the critical value for convection to begin, so that the vertical forces on a convecting air mass are always approximately in balance. Use the result of Problem 1 (b) to find a formula for dT/dz in this case. The result should be a constant, independent of temperature and pressure, which evaluates to approximately −10°C/km. This fundamental meteorological quantity is known as the dry adiabatic lapse rate.

Problem 1:

The exponential atmosphere.

(a) Consider a horizontal slab of air whose thickness (height) is dz. If this slab is at rest, the pressure holding it up from below must balance both the pressure from above and the weight of the slab. Use this fact to find an expression for dP/dz, the variation of pressure with altitude, in terms of the density of air.

(b) Use the ideal gas law to write the density of air in terms of pressure, temperature, and the average mass m of the air molecules. (The information needed to calculate m is given in Problem 2.) Show, then, that the pressure obeys the differential equation

called the barometric equation.

(c) Assuming that the temperature of the atmosphere is independent of height (not a great assumption but not terrible either), solve the barometric equation to obtain the pressure as a function of height: P(z) = P(0)e−mgz/kT. Show also that the density obeys a similar equation.

(d) Estimate the pressure, in atmospheres, at the following locations: Ogden, Utah (4700 ft or 1430 m above sea level); Leadville, Colorado (10,150 ft, 3090 m) ; Mt. Whitney, California (14,500 ft, 4420 m); Mt. Everest, Nepal/Tibet (29,000 ft, 8850 m). (Assume that the pressure at sea level is 1 atm.)

Problem 2:

Calculate the mass of a mole of dry air, which is a mixture of N2 (78% by volume), O2 (21%), and argon (1%).

Questions & Answers

QUESTION:

Problem 40P

In Problem you calculated the pressure of earth’s atmosphere as a function of altitude, assuming constant temperature. Ordinarily, however, the temperature of the bottommost 10–15 km of the atmosphere (called the troposphere) decreases with increasing altitude, due to heating from the ground (which is warmed by sunlight). If the temperature gradient |dT/dz| exceeds a certain critical value, convection will occur: Warm, low-density air will rise, while cool, high-density air sinks. The decrease of pressure with altitude causes a rising air mass to expand adiabatically and thus to cool. The condition for convection to occur is that the rising air mass must remain warmer than the surrounding air despite this adiabatic cooling.

(a) Show that when an ideal gas expands adiabatically, the temperature and pressure are related by the differential equation

(b) Assume that dT/dz is just at the critical value for convection to begin, so that the vertical forces on a convecting air mass are always approximately in balance. Use the result of Problem 1 (b) to find a formula for dT/dz in this case. The result should be a constant, independent of temperature and pressure, which evaluates to approximately −10°C/km. This fundamental meteorological quantity is known as the dry adiabatic lapse rate.

Problem 1:

The exponential atmosphere.

(a) Consider a horizontal slab of air whose thickness (height) is dz. If this slab is at rest, the pressure holding it up from below must balance both the pressure from above and the weight of the slab. Use this fact to find an expression for dP/dz, the variation of pressure with altitude, in terms of the density of air.

(b) Use the ideal gas law to write the density of air in terms of pressure, temperature, and the average mass m of the air molecules. (The information needed to calculate m is given in Problem 2.) Show, then, that the pressure obeys the differential equation

called the barometric equation.

(c) Assuming that the temperature of the atmosphere is independent of height (not a great assumption but not terrible either), solve the barometric equation to obtain the pressure as a function of height: P(z) = P(0)e−mgz/kT. Show also that the density obeys a similar equation.

(d) Estimate the pressure, in atmospheres, at the following locations: Ogden, Utah (4700 ft or 1430 m above sea level); Leadville, Colorado (10,150 ft, 3090 m) ; Mt. Whitney, California (14,500 ft, 4420 m); Mt. Everest, Nepal/Tibet (29,000 ft, 8850 m). (Assume that the pressure at sea level is 1 atm.)

Problem 2:

Calculate the mass of a mole of dry air, which is a mixture of N2 (78% by volume), O2 (21%), and argon (1%).

ANSWER:

Solution 40P

a.)

The barometric equation in Problem 1 was derived under the assumption that the atmosphere is stable, so that at a given height , the pressure is equal to the weight of the column of air of unit cross-sectional area above that altitude. The barometric equation is

=  ……    (1)

Earlier, we assumed that  was constant, which allowed us to integrate the equation. In reality, the temperature decreases with increasing . If the temperature gradient passes a critical value, the density of the warmer air near the surface drops to a point where it starts to rise, resulting in convection, or the mass movement of air. Similarly, the density of the cooler air higher up is large enough that it falls towards the surface, so that a cycle is set up

If we assume that the velocity of these air masses is high enough that little heat is lost or gained as the air moves vertically, we can use the adiabatic formula to analyze the situation.

For adiabatic expansion, the pressure, volume and temperature are related by

=

=

Where and  are constants and = (+2)/

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