Consider the following reaction: At 25C, the following two

Chapter 12, Problem 108

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Consider the following reaction: At 25C, the following two experiments were run, yielding the following data: Experiment 1: [Y]0 3.0 M CH3X Y CH3Y X Experiments also were run at 85C. The value of the rate constant at 85C was found to be 7.88 108 (with the time in units of hours), where [CH3X]0 1.0 102 M and [Y]0 3.0 M. a. Determine the rate law and the value of k for this reaction at 25C. b. Determine the half-life at 85C. c. Determine Ea for the reaction. d. Given that the CX bond energy is known to be about 325 kJ/mol, suggest a mechanism that explains the results in parts a and c. [C

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