Plot the van der Waals isotherm for T/Tc = 0.95, working

Chapter 5, Problem 52P

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Problem 52P

Plot the van der Waals isotherm for T/Tc = 0.95, working in terms of reduced variables. Perform the Maxwell construction (either graphically or numerically) to obtain the vapour pressure. Then plot the Gibbs free energy (in units of NkTc) as a function of pressure for this same temperature and check that this graph predicts the same value for the vapor pressure.

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