Derive the van’t Hoff equation, which gives the dependence
Chapter 5, Problem 85P(choose chapter or problem)
Problem 85P
Derive the van’t Hoff equation,
which gives the dependence of the equilibrium constant on temperature. Here ΔH° is the enthalpy change of the reaction, for pure substances in their standard states (1 bar pressure for gases). Notice that if ΔH° is positive (loosely speaking, if the reaction requires the absorption of heat), then higher temperature makes the reaction tend more to the right, as you might expect. Often you can neglect the temperature dependence of ΔH°; solve the equation in this case to obtain
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