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Derive equations and for entropy and chemical potential of
Chapter 6, Problem 45P(choose chapter or problem)
Problem 45P
Derive equations and for entropy and chemical potential of an ideal gas.
Equation 1:
Equation 2:
Questions & Answers
QUESTION:
Problem 45P
Derive equations and for entropy and chemical potential of an ideal gas.
Equation 1:
Equation 2:
ANSWER:
Step 1 of 3
Use the equation 6.90 and the Helmholtz free energy of the ideal gas system.
Here is the internal contribution to Helmholtz free energy of the ideal gas system, is the number of molecules in the ideal gas, is the Boltzmann’s constant, is the temperature of the ideal gas, is the volume of the ideal gas system, and is the quantum volume.
The quantum volume of the system is given by,
Here is the planck’s constant and is the mass of the molecules of the ideal gas.