For a mole of nitrogen (N2) gas at room temperature and

Chapter 6, Problem 49P

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QUESTION:

For a mole of nitrogen \(\left(\mathrm{N}_{2}\right)\) gas at room temperature and atmospheric pressure, compute the following: U, H, F, G, S, and \(\mu\). (The electronic ground state of nitrogen is not degenerate.)

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QUESTION:

For a mole of nitrogen \(\left(\mathrm{N}_{2}\right)\) gas at room temperature and atmospheric pressure, compute the following: U, H, F, G, S, and \(\mu\). (The electronic ground state of nitrogen is not degenerate.)

ANSWER:

Step 1 of 12

Take into account that we have one mole of nitrogen at normal temperature T = 298 K, the mass of the nitrogen molecule \(N_{2}\) is 28 u, where \(u=1.66 \times 10^{-27} \mathrm{~kg}\).

The total energy is given by:

\(U=\frac{3}{2} N k T+U_{i n t}\)

where,

\(U_{\text {int }}=\frac{f}{2} N k T\)

So,

\(U=\frac{3}{2} N k T+\frac{f}{2} N k T\)

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