Consider the following reaction between mercury(ll)

Chemistry: The Central Science | 13th Edition | ISBN: 9780321910417 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus

ISBN: 9780321910417 77

Solution for problem 93AE Chapter 14

Chemistry: The Central Science | 13th Edition

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Problem 93AE

Consider the following reaction between mercury(ll) chloride and oxalate ion:

2 HgCI2(aq) + C2O42 - (ag) → 2 Cl- (aq) + 2 CO2(g) + Hg2CI2(s)

The initial rate of this reaction was determined for several concentrations of HgCI2 and C2O4 2-, and the following rate data were obtained for the rate of disappearance of C2O4 2 -:

(a) What is the rate law for this reaction? (b) What is the value of the rate constant with proper units? (c) What is the reaction rate when the initial concentration of HgCI2 is 0.100 M and that of (C2O4 2-) is 0.25 M if the temperature is the same as that used to obtain the data shown?

Step-by-Step Solution:

Step 1 of 3

Chapter 6: Properties and Reactions of Haloalkanes A. Physical Properties of Haloalkanes a. Bond strength of C-X decreases as the size of X increases i. C-X b ond length increases 1. As size of X increases, bond overlap between C and X decreases b. C-X b ond is polarized i. Electrophilic partial positive C atom is subject to attack by anions and other nucleophiles ii. Cations and other electrophiles attack the partial negative X atom c. Haloalkanes have h igher boiling poin

Step 2 of 3

Chapter 14, Problem 93AE is Solved

Step 3 of 3

Textbook: Chemistry: The Central Science

Edition: 13

Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus

ISBN: 9780321910417

The full step-by-step solution to problem: 93AE from chapter: 14 was answered by , our top Chemistry solution expert on 09/04/17, 09:30PM. This textbook survival guide was created for the textbook: Chemistry: The Central Science, edition: 13. This full solution covers the following key subjects: . This expansive textbook survival guide covers 305 chapters, and 6352 solutions. The answer to “Consider the following reaction between mercury(ll) chloride and oxalate ion:2 HgCI2(aq) + C2O42 - (ag) ? 2 Cl- (aq) + 2 CO2(g) + Hg2CI2(s)The initial rate of this reaction was determined for several concentrations of HgCI2 and C2O4 2-, and the following rate data were obtained for the rate of disappearance of C2O4 2 -: (a) What is the rate law for this reaction? (b) What is the value of the rate constant with proper units? (c) What is the reaction rate when the initial concentration of HgCI2 is 0.100 M and that of (C2O4 2-) is 0.25 M if the temperature is the same as that used to obtain the data shown?” is broken down into a number of easy to follow steps, and 113 words. Chemistry: The Central Science was written by and is associated to the ISBN: 9780321910417. Since the solution to 93AE from 14 chapter was answered, more than 254 students have viewed the full step-by-step answer.