The mechanism for the oxidation of HBr by 02 to form 2 H20 and Br2 is shown in Exercise, (a) Calculate the overall standard enthalpy change for the reaction process, (b) HBr does not react with 02 at a measurable rate at room temperature under ordinary conditions. What can you infer from this about the magnitude of the activation energy for the rate-determining step? (c) Draw a plausible Lewis structure for the intermediate HOOBr. To what familiar compound of hydrogen and oxygen does it appear similar?
Reaction Mechanisms (Section)
You have studied the gas-phase oxidation of HBr by 02:
4 HBr(g) + 02(g)—2 H20(g) + 2 Br2(g)
You find the reaction to be first order with respect to HBr and first order with respect to 02. You propose the following mechanism:
HBr(g) + 02(g)- HOOBr(g)
HOOBr(g) + HBr(g)—2 HOBr(g)
HOBr(g) + HBr(g)— H20(g) + Br2(g)
(a) Confirm that the elementary reactions add to give the overall reaction, (b) Based on the experimentally determined rate law, which step is rate determining? (c) What are the intermediates in this mechanism? (d) If you are unable to detect HOBr or HOOBr among the products, does this disprove your mechanism?
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