The Molecular Interpretation of

Chapter , Problem 42E

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Problem 42E

Problem

The Molecular Interpretation of Entropy and the Third Law of Thermodynamics (Section)

For each of the following pairs, indicate which substance possesses the larger standard entropy: (a) 1 mol of P4(g) at 300 "C, 0.01 atm, or 1 mol of As4(g) at 300 "C, 0.01 atm; (b) 1 mol of H20(g) at 100 "C, 1 atm, or 1 mol of H20(!) at100 °C, 1 atm; (c) 0.5 mol of N2(g) at 298 K, 20-L volume, or 0.5 mol CH4(g) at 298 K, 20-L volume; (d) 100 g Na2S04(s) at 30 "C or 100 g Na2S04(^ at 30 °C.

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