Solved: A voltaic cell is based on Ag+(aq)/Ag(s) and

Chapter , Problem 114IE

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Problem 114IE

A voltaic cell is based on Ag+(aq)/Ag(s) and Fe3+(aq)/Fe2+(aq) half-cells. (a) What is the standard emf of the cell? (b) Which reaction occurs at the cathode and which at the anode of the cell? (c)Use S° values in Appendix C and the relationship between cell potential and free-energy change to predict whether the standard cell potential increases or decreases when the temperature is raised above 25 °C.

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