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Color and Magnetism in Coordination Chemistry; | Ch 23 - 54E

Chemistry: The Central Science | 13th Edition | ISBN: 9780321910417 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus ISBN: 9780321910417 77

Solution for problem 54E Chapter 23

Chemistry: The Central Science | 13th Edition

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Chemistry: The Central Science | 13th Edition | ISBN: 9780321910417 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus

Chemistry: The Central Science | 13th Edition

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Problem 54E

Color and Magnetism in Coordination Chemistry; Crystal-Field Theory (Sections)

The color and wavelength of the absorption maximum for [Ni(H2O)6]2+, [Ni(NH3)6]2+, and [Ni(en)3]2+ are given in Figure. The absorption maximum for the [Ni(bipy)3]2+ ion occurs at about 520 nm.

If you were to use a ligand L that was a stronger field ligand than ethylenediamine, what color would you expect the [NiL6]2+ complex ion to have? (a) What color would you expect for the [Ni(bipy)3]2+ ion? (b) Based on these data, where would you put bipy in the spectrochemical series?

▲ Figure Effect of ligand on crystal-field splitting. The greater the crystal-field strength of the ligand, the greater the energy gap Δ it causes between the t2 and e sets of the metal ion’s orbitals. This shifts the wavelength of the absorption maximum to shorter values.

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CHM 103 Week 6 Notes de Broglie Wavelength:  If light behaves like a particle and a wave, matter also can  Equation: λ = h/mv, where h is Planck’s constant, m is mass of object, and v is speed of object Heisenberg Uncertainty Principle  An electron path is not certain  This means that it is impossible to know both the position and the speed of a particle simultaneously (think of taking the temperature of a cup of coffee example)  This is important because it shows that the Bohr Model of the atom works well for hydrogen but no other elements Quantum Mechanical Model  Bohr is the classical model (electrons travel in orbits), only works when we know where the electrons are  Using the qua

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Chapter 23, Problem 54E is Solved
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Textbook: Chemistry: The Central Science
Edition: 13
Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward; Matthew E. Stoltzfus
ISBN: 9780321910417

Since the solution to 54E from 23 chapter was answered, more than 425 students have viewed the full step-by-step answer. The full step-by-step solution to problem: 54E from chapter: 23 was answered by , our top Chemistry solution expert on 09/04/17, 09:30PM. The answer to “Color and Magnetism in Coordination Chemistry; Crystal-Field Theory (Sections)The color and wavelength of the absorption maximum for [Ni(H2O)6]2+, [Ni(NH3)6]2+, and [Ni(en)3]2+ are given in Figure. The absorption maximum for the [Ni(bipy)3]2+ ion occurs at about 520 nm.If you were to use a ligand L that was a stronger field ligand than ethylenediamine, what color would you expect the [NiL6]2+ complex ion to have? (a) What color would you expect for the [Ni(bipy)3]2+ ion? (b) Based on these data, where would you put bipy in the spectrochemical series?? Figure Effect of ligand on crystal-field splitting. The greater the crystal-field strength of the ligand, the greater the energy gap ? it causes between the t2 and e sets of the metal ion’s orbitals. This shifts the wavelength of the absorption maximum to shorter values.” is broken down into a number of easy to follow steps, and 132 words. Chemistry: The Central Science was written by and is associated to the ISBN: 9780321910417. This full solution covers the following key subjects: . This expansive textbook survival guide covers 305 chapters, and 6352 solutions. This textbook survival guide was created for the textbook: Chemistry: The Central Science, edition: 13.

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Color and Magnetism in Coordination Chemistry; | Ch 23 - 54E