Problem 100
Estimate the boiling point of water in Leadville, Colorado, elevation 3170 m. To do this, use the barometric formula relating pressure and altitude: pressure in atm; due to gravity; molar mass of air, and T is the Kelvin temperature). Assume the air temperature is and that
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November 10 Will not be on an exam Gilman Reagent R' adds twice Gilman is the least reactive reagent. It can't react with the ketone. Don't worry about anhydrides or thioesters. Don't worry about amides. Enols, Enolates, and Carbonyl Condensations Chapter 22 Beta proton pKa ~45 Aldehydes/ketones ~15-20 Esters ~25 Alpha proton pKa depends Nitriles ~25 Alpha protons are significantly more acidic than beta protons. November 12 Base: "Enol-Keto Tautame
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Chapter 12, Problem 100 is Solved
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