As a sodium chloride solution is added to a solution of

Chapter 8, Problem 8.131

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As a sodium chloride solution is added to a solution of silver nitrate, a white precipitate forms. Ammonia is added to the mixture and the precipitate dissolves. When potassium bromide solution is then added, a pale yellow precipitate appears. When a solution of sodium thiosulfate is added, the yellow precipitate dissolves. Finally, potassium iodide is added to the solution and a yellow precipitate forms. Write reactions for all the changes mentioned above. What conclusions can you draw concerning the sizes of the Ksp values for AgCl, AgBr, and AgI? What can you say about the relative values of the formation constants of Ag(NH3)2 1 and Ag(S2O3)2 32?

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