Consider a sample containing 5.00 moles of a monatomic

Chapter 9, Problem 9.126

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Consider a sample containing 5.00 moles of a monatomic ideal gas that is taken from state A to state B by the following two pathways: Pathway one: PA 5 3.00 atm 1 PC 5 3.00 atm VA 5 15.0 L 88n VC 5 55.0 L 2 PB 5 6.00 atm 88n VB 5 20.0 L Pathway two: PA 5 3.00 atm 3 PD 5 6.00 atm VA 5 15.0 L 88n VD 5 15.0 L 4 PB 5 6.00 atm 88n VB 5 20.0 L For each step, assume that the external pressure is constant and equals the final pressure of the gas for that step. Calculate q, w, DE, and DH for each step, and calculate overall values for each pathway. Explain how the overall values for the two pathways illustrate that DE and DH are state functions, whereas q and w are path functions.

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