Show that for nonstandard conditions the temperature

Chapter 20, Problem 99

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Show that for nonstandard conditions the temperature variation of a cell potential is E1T12 - E1T22 = 1T1 - T22 1S - R ln Q2 zF where are the cell potentials at respectively. We have assumed that the value of Q is maintained at a constant value. For the nonstandard cell below, the potential drops from 0.394 V at 50.0 to 0.370 V at 25.0 Calculate Q, for the reaction, and calculate K for the two temperatures. Choose concentrations of the species involved in the cell reaction that give the value of Q that you have calculated, and then determine the equilibrium concentrations of the species at 50.0

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