Solution: Carbon monoxide is toxic because it bonds much

Chapter 10, Problem 10.88

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Carbon monoxide is toxic because it bonds much more strongly to the iron in hemoglobin (Hgb) than does O2. Consider the following reactions and approximate standard free energy changes: Hgb 1 O2 88n HgbO2 DG8 5 270 kJ Hgb 1 CO 88n HgbCO DG8 5 280 kJ Using these data, estimate the equilibrium constant value at 258C for the following reaction: HgbO2 1 CO 34 HgbCO 1 O2

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