Solved: Consider two perfectly insulated vessels. Vessel 1

Chapter 10, Problem 10.143

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Consider two perfectly insulated vessels. Vessel 1 initially contains an ice cube at 08C and water at 08C. Vessel 2 initially contains an ice cube at 08C and a saltwater solution at 08C. Consider the process H2O(s) n H2O(l). a. Determine the sign of DS, DSsurr, and DSuniv for the process in vessel 1. b. Determine the sign of DS, DSsurr, and DSuniv for the process in vessel 2. (Hint: Think about the effect that a salt has on the freezing point of a solvent.)

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